Numerical simulation of concentration over-voltage in a polymer electrolyte fuel cell under low-hydrogen conditions

Yamamoto, T. and Ishimaru, K. and Osman, K. and Kori, M. I. and Khudzari, A. Z. M. and Taib, I. and Yamamoto, T. (2018) Numerical simulation of concentration over-voltage in a polymer electrolyte fuel cell under low-hydrogen conditions. International Journal of Integrated Engineering, 10 (4). pp. 88-94. ISSN 2229-838X

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Abstract

This article elucidates the effect of low hydrogen concentration fuel gas on polymer electrolyte fuel cell (PEFC) performance, with particular emphasis on the transport of chemical species in the anode separator channel and the electrochemical reactions. A numerical simulation model for PEFCs was developed; the model combined a computational fluid dynamics model for mass transfer in the anode separator and the gas diffusion layer(GDL)as well as a PEFC electrochemical reaction model takinginto account the activation, concentration, and resistance over-voltages. The emphasis in this study is placed on obtaining a basic understanding of how three-dimensional flow and low-hydrogen fuel transport phenomena in the anode separator channelimpactthe electrochemical processes occurring in PEFCs. Comparison of the numerical simulation results with experimental data indicates that the performance degradation in PEFCs is negligible for hydrogen concentrations over 30%, whereas it becomes significant for concentrations below 10%. Furthermore, the numerical simulationresults showthat controlling the fuel supply flow rate stimulates hydrogen transport inthe GDL and the catalyst layer, which consequently enhances PEFC performance under low-hydrogen conditions.

Item Type:	Article
Uncontrolled Keywords:	Polymer electrolyte fuel cell; concentration over-voltage; computer fluid dynamics; electrochemical reaction model; Low hydrogen fuel gasfuel
Subjects:	T Technology > TJ Mechanical engineering and machinery > TJ170-179 Mechanics applied to machinery. Dynamics T Technology > TP Chemical technology > TP1080-1185 Polymers and polymer manufacture
Divisions:	Faculty of Mechanical and Manufacturing Engineering > Department of Mechanical Engineering
Depositing User:	UiTM Student Praktikal
Date Deposited:	25 Nov 2021 06:40
Last Modified:	25 Nov 2021 06:40
URI:	http://eprints.uthm.edu.my/id/eprint/4179

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